THWN is rated for wet locations
As Ecnerwal discusses.
The issue is thermal
The difference is at the top of Table 310.15(B)(16).
- THWN is allowed 75 degree C running temperature.
- THWN-2 is allowed 90 degrees C.
- THHN also is allowed 90 C
Southwire is making a disclaimer: they are saying they don’t guarantee #14-10 will be THWN-2. What’s on their mind is a different table, NEC 240.4(D), which places artificial limits on #14, #12 and #10 wires, to limit them to 15A, 20A and 30A regardless of tables or thermal calcs.
Their logic is “heck, you can’t run these wires at thermal limits anyway, so why do they need to be -2?”
However this still can bite you if you have multiple circuits in the pipe. You must still do thermal derate calcs based on 310.15(B)(3)(a). Those derate calcs come off the highest temp allowed for the insulation. If the wire is THWN and not THWN-2, you’re forced to calculate off the 75C number instead of the 90C number. That won’t make a difference with up to 3 circuits in single/split-phase territory (2 in 3-phase territory) but it’ll be problem getting to 4 circuits (or 3 in 3ph).
Cable in conduit is about swept area
Anytime you put a non-round cable in a conduit, you must treat it like helicopter blades: it occupies space like a round wire of the large dimension. Because it twists.
This means an oval cable, especially a very wide oval cable like UF, sweeps an awful lot of area in the conduit - to the point that UF requires outlandishly large pipe. One 6/3 UF requires a 2” pipe, no kidding, do the calc yourself! Here’s Harper’s shortcut: A single cable needs 138% of its wide width as the interior dimension of the conduit, but this gets much worse if there are 2+ wires present.
NM or NM-B is already wrong in outdoor conduit because of the “wet rating” problem of course, but UF isn’t an automatic upgrade because UF takes more space.
You do need to remove the NM-B, but not just over the wet rating; it’s because the circular area of the NM-B, plus the #8 wires, has most likely overstuffed the conduit.